According to 2001/58/EC
MATERIAL SAFETY DATA SHEET
Catalogue N° : 140559 Printing date : 20/05/2007
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY
1.1. Identification of the substance or preparation
ECOWASH
1.2. Use of the substance/preparation
Washing fluid for offset printing machines
1.3. Company/undertaking identification
FUJIFILM Europe NV
EUROPARK-NOORD 21-22
B-9100 SINT NIKLAAS
TEL : +32 (3)760 02 00
FAX : +32 (3)776 91 22
1.4. Emergency telephone
+32 (0)3 760 02 00
2. COMPOSITION / INFORMATION ON INGREDIENTS
Components contributing to hazard:
w/w%
CAS N°
EINECS N°
Chemical Name
Symb.R-phrases
15-30
.
8028-48-6
.
232-433-8
.
ORANGENTERPENE
Xn R:10-38-65
3. HAZARDS IDENTIFICATION
Most important hazards :
Flammable.
Irritating to skin.
Harmful: may cause lung damage if swallowed.
4. FIRST AID MEASURES
Eye contact
Irrigate with flowing water immediately and continuously for 15 minutes.
Consult medical personnel.
Skin contact
Immediately flush with plenty of water for at least 15 minutes while
removing contaminated clothing
Ingestion
Do not induce vomitting. Give large amounts of water or milk if available
and transport to medical facility.
Inhalation
Remove to fresh air. Consult a physician.
Further information
None
5. FIRE-FIGHTING MEASURES
5.1. Suitable extinguishing media:
Water fog, carbon dioxide, foam, dry chemicals.
5.2. Extinguishing media to avoid:
Water.
5.3. Further information:
Keep containers cool by spraying with water.
6. ACCIDENTAL RELEASE MEASURES
- Wear adequate personal protective equipment, see section 8 ( exposure
control / personal protection ).
- Spills should be contained by and carried with suitable absorbent
material and removed from disposal.
- Dispose of according to local and national regulations.
- Prevent from entering into soil, waterways and groundwater.
7. HANDLING AND STORAGE
7.1. Handling
Avoid eye and skin contact. Wash hands and exposed skin before eating,
drinking or smoking and after work. Use only in a well ventilated area.
Ingestion, exposure to skin and eyes and inhalation of any generated
vapours should be avoided. Wear suitable protective clothing, gloves and
eye/face protection. Do not consume or store food in the working area.
7.2. Storage
Keep containers tightly closed. Store in a well ventilated, cool, dry area.
Take measures to prevent electrostatic charging.
Explosible with air in a vaporous/gaseous state.
Storage class : 3A (VCI storage system), Vbf A II
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1. Exposure limit values (INGREDIENTS INFORMATION)
8.2. Exposure controls
Respiratory protection: no respiratory protection needed under normal
conditions. Good ventilation should be sufficient.
Hand protection: use chemical resistant gloves. In case of prolonged
immersion or frequently repeated contact use gloves made of the material :
nitrile rubber.
Eye protection: use chemical safety goggles. Eye wash fountain should be
located in immediate work area.
Other: appropriate protective clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Liquid
Colour : Colourless
Odour : Orange
Flash point °C : 53
Density (20°C) Kg/L : 0,962
Solubility in water (25°C) : Soluble in Water
10. STABILITY AND REACTIVITY
10.1. Conditions to avoid
Heating.
The product is stable under normal storage conditions.
10.2. Materials to avoid
Keep away from oxidising material(s).
10.3. Hazardous decomposition products
Formation of CO2 and CO fumes is possible.
11. TOXICOLOGICAL INFORMATION
Acute toxicity (INGREDIENTS INFORMATION)
ORANGENTERPENE
LD50 (Oral Rat) = > 4400 mg/kg
LD50 (Dermal rabbit) = > 2000 mg/kg
Skin contact
Irritating to skin.
Further information
Harmful: may cause lung damage if swallowed.
12. ECOLOGICAL INFORMATION
12.1. Ecotoxicity
ORANGENTERPENE
LC50 (Fish, 96 hours) = NA
12.2. Mobility
not known
12.3. Persistence and Degradability
not known
12.4. Bioaccumulative potential
not known
12.5. Other adverse effects
13. DISPOSAL CONSIDERATIONS
Dispose of according to local and national regulations. Containers must be
disposed of in accordance with local regulations.
EAK : 07 06 04 Other organic solvents, cleaning agents and mother liquor.
14. TRANSPORT INFORMATION
UN N° : 2319 PSN : TERPENE HYDROCARBONS, N.O.S.
(Orangeterpene)
ADR/RID
Class:3 labels :3 Pack. Group:III
Code :E TREMcard :3.2319A-310 Spec. Prov.:-
Pack. Inst.:P001,IBC03,LP01,R001 Lim. Quant.:LQ7
IMDG
Class:3 Subs. Risk :NA Pack. Group:III
EmS fire:F-E EmS Storage:S-D IBC. Inst. :IBC03
Pack. Inst.:P001,LP01 Lim. Quant.:5L Mar.Poll:Y
ICAO/IATA
Class:3 Subs. Risk :NA Pack. Group:III
Passenger and Cargo Aircraft. Pkg Inst:309 Max Net Qty/Pkg:60L
Cargo Aircraft Only . Pkg Inst:310 Max Net Qty/Pkg:220L
Ltd Qty . Pkg Inst:10L Max Net Qty/Pkg:Y309
15. REGULATORY INFORMATION
EU Classification and User Label Information:
Contains : ORANGENTERPENE
Symbol(s) : Xn
R(isk) phrase(s) :
R10 : Flammable.
R38 : Irritating to skin.
R65 : Harmful: may cause lung damage if swallowed.
S(afety) phrase(s) :
S23 : Do not breathe vapour.
S24 : Avoid contact with skin.
S28 : After contact with skin, wash immediately with plenty of ... (to be
specified by the manufacturer).
S62 : If swallowed, do not induce vomiting: seek medical advice immediately and
show this container or label.
Other information :
Nota P ( 2001/58/EC ) : < 0,1 % Benzene ( CAS 71-43-2, EC 200-753-7 )
Explosible with air in a vaporous/gaseous state.
WGK: 1
16. OTHER INFORMATION
The use of the preparation is restricted to professional users|
The above mentioned data correspond to our present state of knowledge and
experience. The safety data sheet serves as description of the products in
regard to necessary safety measures. The indications have not the meaning
of guarantees on properties.
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Date of issue: 01.10.2005
Supersedes edition of: 01.04.2004
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NAv : Not available NA : Not applicable
RISK PHRASES MENTIONED IN PARAGRAPH 2:
R10 : Flammable.
R38 : Irritating to skin.
R65 : Harmful: may cause lung damage if swallowed.
