According to 2001/58/EC
MATERIAL SAFETY DATA SHEET
Catalogue N° : 03022D03 Printing date : 20/05/2007
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY
1.1. Identification of the substance or preparation
ALUNET
1.2. Use of the substance/preparation
Cleaner for offset printing plates
1.3. Company/undertaking identification
FUJIFILM Europe NV
EUROPARK-NOORD 21-22
B-9100 SINT NIKLAAS
TEL : +32 (3)760 02 00
FAX : +32 (3)776 91 22
1.4. Emergency telephone
+32 (0)3 760 02 00
2. COMPOSITION / INFORMATION ON INGREDIENTS
Components contributing to hazard:
w/w%
CAS N°
EINECS N°
Chemical Name
Symb.R-phrases
20-40
.
1-5
.
1-5
.
64742-48-9
.
7664-38-2
.
103819-01-8
.
265-150-3
.
231-633-2
.
.
.
MIXTURE OF HYDROCARBONS FREE OF AROMATES
Xn R:65-66
PHOSPHORIC ACID
C R:34
FAT ALCOHOL ALCOXYLATE POLYMER
Xi N R:38-50
3. HAZARDS IDENTIFICATION
Most important hazards :
Not classified as a hazardous product conform EEC Dangerous Substances
Directive and Dangerous Preparation Directive.
4. FIRST AID MEASURES
Eye contact
Irrigate with flowing water immediately and continuously for 15 minutes.
Consult medical personnel.
Skin contact
Immediately flush with plenty of water for at least 15 minutes while
removing contaminated clothing
Ingestion
Consult a physician or transport to emergency facility immediately
Inhalation
Remove to fresh air. Consult a physician.
Further information
None
5. FIRE-FIGHTING MEASURES
5.1. Suitable extinguishing media:
Water fog, carbon dioxide, foam, dry chemicals.
Water jet.
5.2. Extinguishing media to avoid:
None.
5.3. Further information:
Keep containers cool by spraying with water.
6. ACCIDENTAL RELEASE MEASURES
- Wear adequate personal protective equipment, see section 8 ( exposure
control / personal protection ).
- Spills should be contained by and carried with suitable absorbent
material and removed from disposal.
- Dispose of according to local and national regulations.
- Prevent from entering into soil, waterways and groundwater.
7. HANDLING AND STORAGE
7.1. Handling
Avoid eye and skin contact. Wash hands and exposed skin before eating,
drinking or smoking and after work. Use only in a well ventilated area.
Ingestion, exposure to skin and eyes and inhalation of any generated
vapours should be avoided. Wear suitable protective clothing, gloves and
eye/face protection. Do not consume or store food in the working area.
7.2. Storage
Keep containers tightly closed. Store in a well ventilated, cool, dry area.
Storage class : 8B (VCI storage system).
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1. Exposure limit values (INGREDIENTS INFORMATION)
MIXTURE OF HYDROCARBONS FREE OF AROMATES
MAK ( Deutschland, TRGS 900 ) = 200 ppm - 1000 mg/m³
FAT ALCOHOL ALCOXYLATE POLYMER
MAK ( Deutschland, TRGS 900 ) = NAv
8.2. Exposure controls
Respiratory protection: no respiratory protection needed under normal
conditions. Good ventilation should be sufficient.
Hand protection: use chemical resistant gloves. In case of prolonged
immersion or frequently repeated contact use gloves made of the materials:
nitrile rubber (thickness >= 0,38 mm, breakthrough time > 480 min)
neoprene (thickness >= 0,65 mm, breakthrough time > 240 min).
butyl rubber (thickness >= 0,36 mm, breakthrough time > 480 min)
For intermittent splash protection corresponding gloves with breakthrough
time > 60 min can be used.
Avoid gloves made of : natural rubber.
Eye protection: use chemical safety goggles. Eye wash fountain should be
located in immediate work area.
Other: appropriate protective clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Viscous
Colour : White
Odour : Mild
Boiling point/range : ~ 100°C
Density (20°C) Kg/L : 0,94
pH value (25°C) : 1,20
Flash point °C : 62
Solubility in water (25°C) : Emulsifiable with water
Viscosity : 60 sec. DIN4 cup
10. STABILITY AND REACTIVITY
10.1. Conditions to avoid
The product is stable under normal storage conditions.
10.2. Materials to avoid
None.
10.3. Hazardous decomposition products
Formation of CO2 and CO fumes is possible.
11. TOXICOLOGICAL INFORMATION
Acute toxicity (INGREDIENTS INFORMATION)
MIXTURE OF HYDROCARBONS FREE OF AROMATES
LD50 (Oral Rat) = NAv
FAT ALCOHOL ALCOXYLATE POLYMER
LD50 (Oral Rat) = > 2000 mg/kg
12. ECOLOGICAL INFORMATION
12.1. Ecotoxicity
MIXTURE OF HYDROCARBONS FREE OF AROMATES
LC50 (Fish, 96 hours) = NAv
FAT ALCOHOL ALCOXYLATE POLYMER
LC50 (Zebra fish, 96h) = 0,1-1 mg/L
12.2. Mobility
not known
12.3. Persistence and Degradability
not known
12.4. Bioaccumulative potential
not known
12.5. Other adverse effects
13. DISPOSAL CONSIDERATIONS
Dispose of according to local and national regulations. Containers must be
disposed of in accordance with local regulations.
EWC: 07 07 01 Aqueous washing liquids and mother liquors.
14. TRANSPORT INFORMATION
UN N° : 3264 PSN : CORROSIVE LIQUID,ACIDIC,INORGANIC,N.O.S.
(Phosphoric acid)
ADR/RID
Class:8 labels :8 Pack. Group:III
Code :E TREMcard :8.3264E-301 Spec. Prov.:274
Pack. Inst.:P001,IBC03,LP01,R001 Lim. Quant.:LQ7
IMDG
Class:8 Subs. Risk :NA Pack. Group:III
EmS fire:F-A EmS Storage:S-B IBC. Inst. :IBC03
Pack. Inst.:P001,LP01 Lim. Quant.:5L Mar.Poll:N
ICAO/IATA
Class:8 Subs. Risk :NA Pack. Group:III
Passenger and Cargo Aircraft. Pkg Inst:818 Max Net Qty/Pkg:5L
Cargo Aircraft Only . Pkg Inst:820 Max Net Qty/Pkg:60L
Ltd Qty . Pkg Inst:1L Max Net Qty/Pkg:Y818
15. REGULATORY INFORMATION
EU Classification and User Label Information:
Not classified as a hazardous product conform EEC Dangerous Substances
Directive and Dangerous Preparation Directive.
Other information :
WGK: 1
BAG T n° (CH): 671 584
Toxicity class (CH): 4
16. OTHER INFORMATION
The use of the preparation is restricted to professional users|
The above mentioned data correspond to our present state of knowledge and
experience. The safety data sheet serves as description of the products in
regard to necessary safety measures. The indications have not the meaning
of guarantees on properties.
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Date of issue: 01.10.2005
Supersedes edition of: 01.04.2004
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NAv : Not available NA : Not applicable
RISK PHRASES MENTIONED IN PARAGRAPH 2:
R34 : Causes burns.
R38 : Irritating to skin.
R50 : Very toxic to aquatic organisms.
R65 : Harmful: may cause lung damage if swallowed.
R66 : Repeated exposure may cause skin dryness or cracking.
